Products Description
What is Phenylmagnesium chloride solut CAS 100-59-4 ?
Phenylmagnesium Chloride (CAS 100-59-4) is an organomagnesium compound with the molecular formula C₆H₅ClMg and a molecular weight of 136.86 g/mol. Its common commercial form is a 2.0 M tetrahydrofuran (THF) solution. The pure product is a colorless to pale yellow liquid with a typical ethereal odor. Also known as Chlorophenylmagnesium.
The density of phenylmagnesium chloride is 0.98 g/mL (20°C, 2.0M THF solution), the melting point is 89–90°C, the boiling point is 230°C (8 Torr), and the flash point is -17°C (highly flammable). It is soluble in aprotic solvents such as THF and ether at room temperature, and reacts violently with water to produce benzene, magnesium hydroxide and hydrogen chloride, releasing a lot of heat. Avoid storing below 25°C to prevent crystallization of magnesium salts (can be dissolved by slight heating).
Basic Info
Phenylmagnesium chloride solut CAS 100-59-4
| CAS | 100-59-4 |
| EINECS | 202-868-8 |
| Molecular Formula | C6H5ClMg |
| Molar Mass | 136.862 |
| Density | 0.98 g/mL at 20 °C |
| Melting Point | 89-90℃ |
| Boling Point | 78.8°C at 760 mmHg |
| Flash Point | 1 °F |
Uses
As a classic Grignard reagent, Phenylmagnesium Chloride is widely used in:
Carbonyl addition reaction: reacts with aldehydes, ketones, and esters to generate tertiary or secondary alcohols (e.g. reacts with benzaldehyde to generate diphenylmethanol);
Metal-catalyzed coupling: participates in Negishi coupling, Kumada coupling, etc., to introduce phenyl groups into aryl/alkenyl halides;
Heterocyclic synthesis: used to construct nitrogen-containing heterocycles (such as indole, pyridine derivatives) and drug intermediates;
Material science: as a precursor for the preparation of organomagnesium catalysts or functional polymers.
Safety Information
Hazards: Highly flammable (H225), water-reactive (H260), corrosive (H314), requires strict isolation from air and moisture.
Handling: Use anhydrous solvents, wear protective equipment in a fume hood, and avoid contact with skin and eyes.
Storage: Store sealed at 2–8°C, away from heat sources and oxidants, and transport according to UN 3399 (flammable organometallic substances).
Company Profile
Gneebio is an enterprise specialising in the research, development, production and sales of phytochemicals and fine chemicals.Our factory was established in 2016 and is located in Henan Province, covering an area of 3,600 square metres. We have a professional, well-equipped and high-quality R&D team with more than 10 years of R&D experience. Our reagent products are widely exported to many countries including the United States, Russia, Canada, Australia, Europe, etc., and we provide fast shipping services to our customers. We hope to establish long-term and mutually beneficial cooperation with more friends in the future and provide the best products and services for our customers.
Contact Us
Tel: +86-372-5055135
Mob: +86-13673325456
Email: sales@gneebio.com
FAQ
Can your company accept customisation and meet customers' special specifications?
Yes, we can.
What are your payment terms?
Wire transfer, paypal, western union, money order and bitcoin.
What is your delivery time?
We usually ship within 1-3 days after receiving your payment.
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