CAS 138124-32-0 | (R,R)-(-)-N N-Bis(3,5-DI-Tert-Butylsalicylidene)-1,2-Cyclohexanediamine-Manganese(Iii) Chloride

(R,R)-(-)-N N-Bis(3,5-DI-Tert-Butylsalicylidene)-1,2-Cyclohexanediamine-Manganese(Iii) Chloride, also known as Jacobson crystals, is a crystalline form of an organic compound. It is a colorless or light yellow crystal that is soluble in organic solvents such as ether, alcohol and benzene. It has low toxicity and low volatility, but is irritating to the eye membrane and skin.

Properties：

1. The core of the compound is a manganese (III) ion, which is connected to two nitrogen-containing and two oxygen-containing Salen ligands.
2. The ligand structure contains two tert-butyl substituents, and these bulky groups can improve the stability and selectivity of the compound.
3. Due to its chiral structure, the compound can catalyze some asymmetric reactions to produce products with high enantioselectivity.

Uses：

1. Mainly used to catalyze asymmetric epoxidation reactions, which are very important in organic synthesis, especially for the synthesis of chiral drugs and pesticides.
2. Also commonly used in the preparation of catalysts, dyes and additives.
3. Used in other types of organic transformations, such as asymmetric cyclopropanation reactions.

1. Care should be taken to prevent contact with skin, eyes and respiratory tract during storage and use.
2. When handling large doses, appropriate protective equipment such as safety glasses, gloves and protective masks should be used.
3. Avoid contact with strong oxidants and fire sources to prevent combustion or explosion.

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